Rheological Properties of Cellulose/Ionic Liquid Solutions: From Dilute to Concentrated States

Abstract : Steady state shear flow of different types of cellulose (microcrystalline, spruce sulfite and bacterial) dissolved in 1-ethyl-3-methylimidazolium acetate was studied in a large range of concentrations (0-15%) and temperatures (0-100 degrees C). Newtonian flow was recorded for all experimental conditions; these viscosity values were used for detailed viscosity-concentration and viscosity-temperature analysis. The exponent in the viscosity-concentration power law was found to be around 4 for temperatures from 0 to 40 degrees C, which is comparable with cellulose dissolved in other solvents, and around 2.5-3 for 60-100 degrees C. Intrinsic viscosities of all celluloses decreased with temperature, indicating a drop in solvent thermodynamic quality with heating. The data obtained can be reduced to a master plot of viscosity versus (concentration x intrinsic viscosity) for all celluloses studied in the whole temperature range. Mark-Houwink exponents were determined: they were lower than that for cellulose dissolved in LiCI/N,N-dimethylacetamide at 30 degrees C and close to theta-value. Viscosity-inverse temperature plots showed a concave shape that is dictated by solvent temperature dependence. The values of the activation energies calculated within Arrhenius approximation are in-line with those obtained for cellulose of comparable molecular weights in other solvents.
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https://hal-mines-paristech.archives-ouvertes.fr/hal-00509464
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Soumis le : jeudi 12 août 2010 - 15:36:59
Dernière modification le : mercredi 7 août 2019 - 15:04:10

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Martin Gericke, Kerstin Schlufter, Tim Liebert, Thomas Heinze, Tatiana Budtova. Rheological Properties of Cellulose/Ionic Liquid Solutions: From Dilute to Concentrated States. Biomacromolecules, American Chemical Society, 2009, 10 (5), pp.1188-1194. ⟨10.1021/bm801430x⟩. ⟨hal-00509464⟩

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