Excess Molar Enthalpies for the Binary and Ternary Mixtures of Cyclohexane, Tetrahydropyran, and Piperidine at 308.15 K and Atmospheric Pressure: Experimental Measurements and Correlations

Farid B. Belaribi (1, 2) , Ghénima Boukais-Belaribi (1) , Amir H. Mohammadi (3) , Dominique Richon (3)

1 USTHB - Université des Sciences et de la Technologie Houari Boumediene = University of Sciences and Technology Houari Boumediene [Alger]
2 CEP - Centre Énergétique et Procédés
3 CEP/Fontainebleau

Excess molar enthalpies for the binary and ternary mixtures of cyclohexane, tetrahydropyran, and piperidine have been measured using a Calvet microcalorimeter at 308.15 K and atmospheric pressure. All of the binary and ternary systems show endothermic behavior. The experimental binary results are correlated using the Redlich−Kister equation. The excess molar enthalpies for the ternary mixture are correlated using the Cibulka equation. The capability of an artificial neural network algorithm to model these data is finally studied.

Domaines: Sciences de l'ingénieur [physics]; Génie des procédés

Farid B. Belaribi, Ghénima Boukais-Belaribi, Amir H. Mohammadi, Dominique Richon. Excess Molar Enthalpies for the Binary and Ternary Mixtures of Cyclohexane, Tetrahydropyran, and Piperidine at 308.15 K and Atmospheric Pressure: Experimental Measurements and Correlations. Journal of Chemical and Engineering Data, 2010, 55 (1), pp.303-307. ⟨10.1021/je900347f⟩. ⟨hal-00509645⟩