Assessment of the Nd/U ratio for the quantification of neodymium in UO2

L. Desgranges (1) , B. Pasquet (2) , I. Roure (2) , S. Portier (3) , S. Bremier , C.T. Walker (4) , R. Hasnaoui (4) , D. Gavillet (5) , M. Martin (5) , Louis Raimbault (6)

1 LCPC - Laboratoire de Caractérisation et d'étude des Propriétés des Combustibles
2 CEA - Commissariat à l'énergie atomique et aux énergies alternatives
3 ITU - JRC Institute for Transuranium Elements [Karlsruhe]
4 IES - JRC Institute for Environment and Sustainability
5 PSI - Paul Scherrer Institute
6 GEOSCIENCES - Centre de Géosciences

The secondary ion energy spectrum of uranium depends on the experimental conditions, which is a problem for the application of a relative sensitivity factor (RSF) procedure for the measurement of the Nd concentration in UO2. This is interpreted as due to the dependence of the sputtering and ionisation yields of uranium on the oxidation state of the surface. Three experimental procedures are being tested to cope with this difficulty.

Mots clés: SIMS; Ionisation yield; Uranium oxide

Domaines: Chimie; Génie chimique

L. Desgranges, B. Pasquet, I. Roure, S. Portier, S. Bremier, et al.. Assessment of the Nd/U ratio for the quantification of neodymium in UO2. Applied Surface Science, 2008, 255 (4), pp.863-865. ⟨10.1016/j.apsusc.2008.05.196⟩. ⟨hal-00569218⟩