Excess Molar Enthalpies for the Binary and Ternary Mixtures of Cyclohexane, Tetrahydropyran, and 1,4-Dioxane at 308.15 K and Atmospheric Pressure: Experimental Measurements and Correlations

Ghénima Boukais-Belaribi (1) , Amir H. Mohammadi (2) , Farid B. Belaribi (1) , Dominique Richon (2)

1 Laboratoire de Thermodynamique et Modélisation Moléculaire
2 CEP/Fontainebleau

Excess molar enthalpies for the binary and ternary mixtures of cyclohexane, tetrahydropyran, and 1,4- dioxane have been measured using a Calvet microcalorimeter at 308.15 K and atmospheric pressure. The experimental binary results are correlated using the Redlich-Kister equation. The excess molar enthalpies for the ternary system are correlated using the Cibulka equation. The capability of the artificial neural network algorithm to model these data is finally studied.

Domaines: Génie des procédés

Ghénima Boukais-Belaribi, Amir H. Mohammadi, Farid B. Belaribi, Dominique Richon. Excess Molar Enthalpies for the Binary and Ternary Mixtures of Cyclohexane, Tetrahydropyran, and 1,4-Dioxane at 308.15 K and Atmospheric Pressure: Experimental Measurements and Correlations. Journal of Chemical and Engineering Data, 2009, 54, pp.2513-2516. ⟨10.1021/je900077g⟩. ⟨hal-00574152⟩