Kinetics of shear-induced gel deswelling/solvent release

Abstract : The previous termkinetics of shear-induced deswelling of gelnext term particles based on synthetic (sodium polyacrylate) and natural (alginate) polymers was studied by rheo-optical technique. A swollen spherical previous termgelnext term particle of 100 ± 50 μm diameter was placed in silicone oil and the evolution of the previous termgelnext term size as a function of time and previous termshearnext term rate was monitored. Different aqueous polymer solutions were used as synthetic previous termgel solvent:next term polyvinylpyrrolidone, hydroxypropyl cellulose and glucose-based polymer. The interfacial tension (previous termgel solvent)next term/(silicone oil), previous termgelnext term degree of swelling, previous termsolventnext term quality and viscosity are the main parameters influencing the previous termkinetics of shear-induced gel deswelling. The kinetics of gelnext term volume loss was approximated by a modified Weibull equation.
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https://hal-mines-paristech.archives-ouvertes.fr/hal-00574188
Contributeur : Magalie Prudon <>
Soumis le : lundi 7 mars 2011 - 13:53:43
Dernière modification le : lundi 12 novembre 2018 - 11:05:17

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Zeo Undina, Elena Tarabukina, Tatiana Budtova. Kinetics of shear-induced gel deswelling/solvent release. Journal of Controlled Release, Elsevier, 2005, 108 (1), pp.Pages 73-83. ⟨10.1016/j.jconrel.2005.07.012⟩. ⟨hal-00574188⟩

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