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Journal articles
Swelling kinetics of a polyelectrolyte gel in water and salt solutions. Coexistence of swollen and collapsed phases
Abstract : The swelling of polyelectrolyte gels in water and salt solutions is associated with the presence of up to three coexisting phases: a dry phase, a swollen phase, and a collapsed one due to the binding of metal ions to polyions. Swelling in pure water proceeds in two ways: a transition from the dry to swollen state, whose kinetics scales with the square of the initial gel size, and a further swelling that scales linearly with the initial gel size. We show that there exist various swelling paths depending on the gel interaction with metal ions and their concentration.
https://hal-mines-paristech.archives-ouvertes.fr/hal-00613101
Contributor : Magalie Prudon Connect in order to contact the contributor
Submitted on : Tuesday, August 2, 2011 - 4:45:07 PM
Last modification on : Wednesday, November 17, 2021 - 12:28:04 PM
Contributor : Magalie Prudon Connect in order to contact the contributor
Submitted on : Tuesday, August 2, 2011 - 4:45:07 PM
Last modification on : Wednesday, November 17, 2021 - 12:28:04 PM
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