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Journal articles

Synthesis and electrical properties of nanostructured Ba2SnYO5.5 proton conductor

Abstract : Ba2SnYO5.5 nanopowders were synthesized by a gel polymerization method. In this process, a gel containing Ba, Sn and Y cations has been obtained by the polymerization of acrylic acid using N,N′-methylene bis-acrylamide as a cross-linking reagent and hydrogen peroxide as an igniting reagent. The gel was calcined at 1200 °C, giving rise to the Ba2SnYO5.5 single-phase nanopowders with the grain size ranging from 50 nm to 70 nm. Nanopowders were sintered at 1150 °C by spark plasma sintering (SPS) to obtain dense nanostructure materials (> 95%) containing grains whose size ranges between 70 nm and 100 nm. Nanostructured Ba2SnYO5.5 shows a good chemical stability in wet atmosphere. However, its protonic conductivity decreases compared with that of microcrystallin Ba2SnYO5.5 ceramics.
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https://hal-mines-paristech.archives-ouvertes.fr/hal-00652957
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Submitted on : Friday, December 16, 2011 - 4:07:03 PM
Last modification on : Tuesday, December 7, 2021 - 2:58:01 PM

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y.Z. Wang, Anthony Chesnaud, Emile Bévillon, Guilhem Dezanneau, Jinlong yang. Synthesis and electrical properties of nanostructured Ba2SnYO5.5 proton conductor. Ceramics International, Elsevier, 2011, 37, pp.3351-3355. ⟨10.1016/j.ceramint.2011.05.135⟩. ⟨hal-00652957⟩

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