Phase Equilibrium Modeling of Structure H Clathrate Hydrates of Methane + Water "Insoluble" Hydrocarbon Promoter Using Group Contribution-Support Vector Machine Technique

Ali Eslamimanesh (1) , Farhad Gharagheizi (2) , Amir H. Mohammadi (1) , Dominique Richon (1) , Mohammad Illbeigi (3) , Alireza Fazlali (3) , Amir Ahmad Forghani (4) , Mohammad Yazdizadeh (5)

1 CEP/Fontainebleau
2 Saman Energy Giti Co.
3 Chemical Engineering Department
4 School of chemical engineering
5 School of chemical and petroleum engineering

In this work, the group contribution (GC) method is coupled with the least-squares support vector machine (LSSVM) mathematical algorithm to develop a model for representation/prediction of the dissociation conditions of structure H (sH) clathrate hydrates of methane with 21 hydrocarbon promoters namely as water "insoluble" promoters. Almost all of available literature data are studied to present a reliable model validated by the following statistical parameters: absolute average relative deviations (AARD) of the represented/predicted dissociation pressures from the reported experimental values: about 1.6%, and squared correlation coefficient: 0.99.

Mots clés: Supercritical Carbon-Dioxide; Natural-Gas Transport; Compositional Analysis; Storage Capacity; Neural-Networks; Solid Compounds; Stability; Hydrogen; System; Optimization

Domaines: Sciences de l'ingénieur [physics]; Génie des procédés

Ali Eslamimanesh, Farhad Gharagheizi, Amir H. Mohammadi, Dominique Richon, Mohammad Illbeigi, et al.. Phase Equilibrium Modeling of Structure H Clathrate Hydrates of Methane + Water "Insoluble" Hydrocarbon Promoter Using Group Contribution-Support Vector Machine Technique. Industrial and engineering chemistry research, 2011, 50 (22), pp.12807-12814. ⟨10.1021/ie2011164⟩. ⟨hal-00656627⟩