Accéder directement au contenu Accéder directement à la navigation
Article dans une revue

Isothermal Vapor−Liquid Equilibrium Data and Thermodynamic Modeling for Binary Systems of Perfluorobutane (R610) + (Methane or Hydrogen Sulfide) at (293, 313, and 333) K

Abstract : Isothermal vapor−liquid equilibrium data for binary system comprising perfluorobutane (R610) with methane (CH4) or hydrogen sulfide (H2S) were measured at isothermal conditions of approximately (293, 313, and 333) K, and pressures up to 9.837 MPa. The data were measured using a “static-analytic” apparatus equipped with a mobile pneumatic capillary sampler. The experimental data were correlated via the direct method using two sets of thermodynamic models. The Peng−Robinson equation of state incorporating the Mathias−Copeman α function, with the Wong−Sandler mixing rule utilizing the nonrandom two-liquid activity coefficient model, was used for the correlation of the CH4 + C4F10 system, while the Soave−Redlich−Kwong equation of state incorporating the Mathias−Copeman α function, with the modified Huron−Vidal first-order mixing rule utilizing the nonrandom two-liquid activity coefficient model was used for the H2S + C4F10 system.
Type de document :
Article dans une revue
Liste complète des métadonnées

https://hal-mines-paristech.archives-ouvertes.fr/hal-01075844
Contributeur : Marie-Claude Watroba <>
Soumis le : lundi 20 octobre 2014 - 14:40:03
Dernière modification le : mercredi 14 octobre 2020 - 04:01:44

Identifiants

Collections

Citation

Mulamba Marc Tshibangu, Alain Valtz, Caleb Narasigadu, Christophe Coquelet, Deresh Ramjugernath. Isothermal Vapor−Liquid Equilibrium Data and Thermodynamic Modeling for Binary Systems of Perfluorobutane (R610) + (Methane or Hydrogen Sulfide) at (293, 313, and 333) K. Journal of Chemical and Engineering Data, American Chemical Society, 2014, 59, pp.2865−2871. ⟨10.1021/je500496y⟩. ⟨hal-01075844⟩

Partager

Métriques

Consultations de la notice

245