Isothermal phase (vapour + liquid) equilibrium data for binary mixturesof propene (R1270) with either 1,1,2,3,3,3-hexafluoro-1-propene (R1216) or 2,2,3-trifluoro-3-(trifluoromethyl)oxirane in the temperature range of (279 to 318) K range.

Shalendra Clinton Subramoney (1) , Wayne Michael Nelson (1) , Xavier Courtial (1) , Paramespri Naidoo (1) , Christophe Coquelet (2) , Dominique Richon (1) , Deresh Ramjugernath (1)

1 Thermodynamics Research Unit
2 CTP - Centre Thermodynamique des Procédés

Isothermal (vapour + liquid) equilibrium data (P–x–y) are presented for the 1-propene +1,1,2,3,3,3-hexafluoro-1-propene and the 1-propene + 2,2,3-trifluoro-3-(trifluoromethyl)oxirane binary systems. Both binary systems were studied at five temperatures, ranging from (279.36 to 318.09) K, at pressures up to 2 MPa. The experimental (vapour + liquid) equilibrium data were measured using an apparatus based on the ‘‘(static + analytic)’’ method incorporating a single movable Rapid On-Line Sampler-Injector to sample the liquid and vapour phases at equilibrium. The expanded uncertainties are approximated on average as = 0.07 K, 0.008 MPa, and 0.007 and 0.009 for the temperature, pressure, and the liquid and vapour mole fractions, respectively. A homogenous maximum-pressure azeotrope was observed for both binary systems at all temperatures studied. The experimental data were correlated with the Peng–Robinson equation of state using the Mathias–Copeman alpha function, paired with the Wong–Sandler mixing rule and the Non-Random Two Liquid activity coefficient model. The model provided satisfactory representation of the phase equilibrium data measured

Mots clés: VLE; Hexafluoropropene; Static + analyti; ROLSI™

Domaines: Génie des procédés

Shalendra Clinton Subramoney, Wayne Michael Nelson, Xavier Courtial, Paramespri Naidoo, Christophe Coquelet, et al.. Isothermal phase (vapour + liquid) equilibrium data for binary mixturesof propene (R1270) with either 1,1,2,3,3,3-hexafluoro-1-propene (R1216) or 2,2,3-trifluoro-3-(trifluoromethyl)oxirane in the temperature range of (279 to 318) K range.. Journal of Chemical Thermodynamics, 2015, 90, pp.100-105. ⟨10.1016/j.jct.2015.06.017⟩. ⟨hal-01202668⟩