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Equilibrium data and GC-PC SAFT predictions for furanic extraction

Abstract : The present study concerns phase equilibria measurements involving oxygenated components (furan and furfural) and potential solvents of extraction (n-hexane, ethanol and n-octanol) using an ebulli-ometer at atmospheric pressure. New liquid-liquid equilibrium data concerning the ternary system furan þ furfural þ n-hexane are also presented. The experimental technique used for the liquid-liquid equilibrium measurements is based on the static analytic method. The two liquid phases are sampled using a syringe and analyzed using gas chromatograph. Two thermodynamic approaches are considered for the data treatment: the first considers a dissymmetric approach using the NRTL activity coefficient model, and the second considers a group contribution model based on the PC-SAFT EoS (GC-PPC SAFT). The experimentally measured data were successfully correlated with the models proposed.
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https://hal-mines-paristech.archives-ouvertes.fr/hal-01371510
Contributor : Marie-Claude Watroba <>
Submitted on : Monday, September 26, 2016 - 3:26:51 PM
Last modification on : Tuesday, December 8, 2020 - 9:55:26 AM
Long-term archiving on: : Tuesday, December 27, 2016 - 12:36:03 PM

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Eric Auger, Christophe Coquelet, Alain Valtz, Mqondisi Nala, Paramespri Naidoo, et al.. Equilibrium data and GC-PC SAFT predictions for furanic extraction. Fluid Phase Equilibria, Elsevier, 2016, 430, pp.57-66. ⟨10.1016/j.fluid.2016.09.019⟩. ⟨hal-01371510⟩

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